Fast and selective synthesis of mono-substituted sucrose methacrylate ester monomer

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Data

2022-01-01

Autores

Rojas Sterling, Juan Camilo
Ortega, Julieth Orduña [UNESP]
Metzker, Gustavo [UNESP]
Boscolo, Mauricio [UNESP]
Mora Vargas, Jorge Andres [UNESP]

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Resumo

Sucrose methacrylate (SM) is a key monomer for synthesizing biocompatible polymers with a carbohydrate core. However, controlled SM synthesis is challenging due to the possible formation of regio-isomers. This study describes SM synthesis that involves ultrasound irradiation of a homogeneous basic medium. The selectivity for mono-substituted SM was 86% within 30 min of reaction. The newly developed methodology is faster and more selective than that of mono-substituted SM synthesis already described in the literature.

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Palavras-chave

Methacrylate, Monomer, Sucrose ester, Ultrasound

Como citar

Carbohydrate Research, v. 511.