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Mechanism of the formation and properties of antimony polyphosphate

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dc.contributor.authorMelnikov, P.
dc.contributor.authorDos Santos, F. J. [UNESP]
dc.contributor.authorSantagnelli, S. B. [UNESP]
dc.contributor.authorSecco, M. A C
dc.contributor.authorGuimarães, W. R.
dc.contributor.authorDelben, A.
dc.contributor.authorDelben, J. R.
dc.contributor.institutionUniversidade Federal de Mato Grosso do Sul (UFMS)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-27T11:21:22Z
dc.date.available2014-05-27T11:21:22Z
dc.date.issued2005-07-01
dc.description.abstractFormation of antimony polyphosphate using Sb2O3 and/or (NH4)2HPO4 and NH4H 2PO4 as starting materials has been simulated by thermal analysis technique. The elimination of water and ammonia molecules induced by heating leads to the formation of intermediate ammonium polyphosphate, which subsequently reacts with Sb2O3. Morphologically, vitreous Sb(PO3)3 is composed of plaques having irregular shapes. Infrared spectra and NMR study is consistent with tetrametaphosphate anion arrangement. The compound is thermally unstable and may be recommended as a donor of -O-P-O- linkers in the preparation of special phosphate glasses. © 2005 Akadémiai Kiadó, Budapest.en
dc.description.affiliationPhysics Department CCET UFMS, Caixa Postal 549, Campo Grande/MS
dc.description.affiliationInstitute of Chemistry UNESP, Rua Prof. Francisco Degni, s/n, CEP 14801-970, Araraquara, SP
dc.description.affiliationUnespInstitute of Chemistry UNESP, Rua Prof. Francisco Degni, s/n, CEP 14801-970, Araraquara, SP
dc.format.extent45-49
dc.identifierhttp://dx.doi.org/10.1007/s10973-005-0743-1
dc.identifier.citationJournal of Thermal Analysis and Calorimetry, v. 81, n. 1, p. 45-49, 2005.
dc.identifier.doi10.1007/s10973-005-0743-1
dc.identifier.issn1388-6150
dc.identifier.scopus2-s2.0-22144470804
dc.identifier.urihttp://hdl.handle.net/11449/68289
dc.identifier.wosWOS:000230263500008
dc.language.isoeng
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.ispartofjcr2.209
dc.relation.ispartofsjr0,587
dc.rights.accessRightsAcesso restrito
dc.sourceScopus
dc.subjectAntimony
dc.subjectGlasses
dc.subjectInorganic materials
dc.subjectPolyphosphate
dc.subjectCrystallization
dc.subjectDifferential thermal analysis
dc.subjectHeating
dc.subjectInfrared spectroscopy
dc.subjectMaterials science
dc.subjectMetallic glass
dc.subjectMorphology
dc.subjectNuclear magnetic resonance
dc.subjectPhosphates
dc.subjectReaction kinetics
dc.subjectAmmonia molecules
dc.subjectPhosphate glasses
dc.subjectAntimony compounds
dc.titleMechanism of the formation and properties of antimony polyphosphateen
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights
dspace.entity.typePublication

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