Biolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processes

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dc.contributor.authorLima, Rosemar de
dc.contributor.authorBento, Heitor B. S. [UNESP]
dc.contributor.authorReis, Cristiano E. R.
dc.contributor.authorVilas Boas, Renata N.
dc.contributor.authorFreitas, Larissa de
dc.contributor.authorCarvalho, Ana K. F.
dc.contributor.authorCastro, Heizir F. de
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionEARTH Univ
dc.contributor.institutionUniv Fed Rural Rio de Janeiro
dc.contributor.institutionUniv Fed Alfenas
dc.date.accessioned2021-06-25T12:16:50Z
dc.date.available2021-06-25T12:16:50Z
dc.date.issued2021-05-19
dc.description.abstractSix lipases were immobilized on a styrene-divinylbenzene support and evaluated on the batch esterification reaction of stearic acid with fusel oil. After a screening design, the two most appropriate lipases were assayed on a packed-bed system, achieving high conversion rates (90-93%) and productivities of isoamyl stearate up to 3144 mmol g(-1) min(-1), which can be used as a substitute to fossil-derived lubricants. Graphicen
dc.description.affiliationUniv Sao Paulo, Engn Sch Lorena, Lorena, SP, Brazil
dc.description.affiliationSao Paulo State Univ, Sch Pharmaceut Sci, Araraquara, SP, Brazil
dc.description.affiliationEARTH Univ, Guacimo, Limon, Costa Rica
dc.description.affiliationUniv Fed Rural Rio de Janeiro, Seropedica, RJ, Brazil
dc.description.affiliationUniv Fed Alfenas, Inst Chem, Alfenas, MG, Brazil
dc.description.affiliationUnespSao Paulo State Univ, Sch Pharmaceut Sci, Araraquara, SP, Brazil
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.description.sponsorshipIdFAPESP: 2016/10636-8
dc.description.sponsorshipIdFAPESP: 2020/15513-7
dc.description.sponsorshipIdCAPES: 001
dc.format.extent12
dc.identifierhttp://dx.doi.org/10.1007/s10562-021-03663-z
dc.identifier.citationCatalysis Letters. New York: Springer, 12 p., 2021.
dc.identifier.doi10.1007/s10562-021-03663-z
dc.identifier.issn1011-372X
dc.identifier.urihttp://hdl.handle.net/11449/209396
dc.identifier.wosWOS:000652091200002
dc.language.isoeng
dc.publisherSpringer
dc.relation.ispartofCatalysis Letters
dc.sourceWeb of Science
dc.subjectEnzymatic catalysis
dc.subjectHeterogeneous catalysis
dc.subjectImmobilization
dc.titleBiolubricant Production from Stearic Acid and Residual Secondary Alcohols: System and Reaction Design for Lipase-Catalyzed Batch and Continuous Processesen
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dcterms.rightsHolderSpringer
unesp.author.orcid0000-0002-0629-3196[2]

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