Silver ion release from electrodes of nanotubes of TiO2 impregnated with Ag nanoparticles applied in photoelectrocatalytic disinfection
Carregando...
Fontes externas
Fontes externas
Data
Orientador
Coorientador
Pós-graduação
Curso de graduação
Título da Revista
ISSN da Revista
Título de Volume
Editor
Elsevier B.V.
Elsevier
Elsevier
Tipo
Artigo
Direito de acesso
Acesso restrito
Fontes externas
Fontes externas
Resumo
Self-organized TiO2 nanotubes arrays electrodes were impregnated with 0-16% of Ag nanoparticles (Ti/TiO2-Ag) using different procedures. The electrodes were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) and photocurrent vs potential curves. The best results were obtained by electrode prepared by photochemical reduction, after immersion in a solution AgNO3 0.05 M (pH 8). The monitoring of Ag+ lixiviation by anodic stripping voltammetry at glassy carbon electrode indicated that a maximum of 2.5 x 10(-6) M is released in the first 40 min of treatment, but it is neglected when used subsequently. Moreover, the antimicrobial behavior of electrodes Ti/TiO2-Ag applied in photoelectrocatalysis presented 100% disinfection in 3 min by using UV irradiation and 99.6% in 30 min with visible irradiation. In addition, the analysis of silver in solution along the reaction shows a negligible lixiviation and a high stability of the surface silver deposits. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.
Descrição
Palavras-chave
Idioma
Inglês
Citação
Journal Of Photochemistry And Photobiology A-chemistry. Lausanne: Elsevier Science Sa, v. 278, p. 1-8, 2014.
