Adhesive Cementation of CAD/CAM Silica-based Ceramics: Effect of Adhesive Type and Long-term Aging on the Bond Strength to Composite Cement

Abstract

Purpose: To investigate the effect of adhesive type and long-term aging on the shear bond strength (SBS) between silica- based ceramics and composite cement (CC). Materials and Methods: Lithium-silicate (LS), feldspathic (FD) and polymer-infiltrated ceramic (PIC) blocks were sectioned (10 x 12 x 2 mm) and divided into 24 groups considering the factors: “ceramics” (LS, FD, and PIC), “adhesive” (Ctrl: without ad- hesive; 2SC: 2-step conventional; 3SC: 3-step conventional; 1SU: 1-step universal), and “aging” (non-aged or aged [A]). After the surface treatments, CC cylinders (n = 15, Ø = 2 mm; height = 2 mm) were made and half of the samples were subjected to thermocycling (10,000) and stored in water at 37°C for 18 months. The samples were submitted to SBS testing (100 kgf, 1 mm/ min) and failure analysis. Extra samples were prepared for microscopic analysis of the adhesive interface. SBS (MPa) data was analyzed by 3-way ANOVA and Tukey’s test (5%). Weibull analysis was performed on the SBS data. Results: All factors and interactions were significant for SBS (p<0.05). Before aging, there was no significant difference be- tween the tested groups and the respective control groups. After aging, the LS_1SU (22.18 ± 7.74) and LS_2SC (17.32 ± 5.86) groups exhibited significantly lower SBS than did the LS_Ctrl (30.30 ± 6.11). Only the LS_1SU group showed a significant de- crease in SBS after aging vs without aging. The LS_1SU (12.20) group showed the highest Weibull modulus, which was signifi- cantly higher than LS_2SC_A (2.82) and LS_1SU_A (3.15) groups. Conclusion: No type of adhesive applied after silane benefitted the long-term adhesion of silica-based ceramics to CC in com- parison to the groups without adhesive.